Green photochemistry: photo-Friedel–Crafts acylations of 1,4-naphthoquinone in room temperature ionic liquids
Murphy, Brian, Goodrich, Peter, Hardacre, Christopher, and Oelgemöller, Michael (2009) Green photochemistry: photo-Friedel–Crafts acylations of 1,4-naphthoquinone in room temperature ionic liquids. Green Chemistry, 11 (11). pp. 1867-1870.
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DOI: 10.1039/b913252j
View at Publisher Website: http://dx.doi.org/10.1039/b913252j
Abstract
The photo-Friedel–Crafts acylation of 1,4-naphthoquinone with various aldehydes was investigated in a series of room temperature ionic liquids. High conversions and selectivities were achieved in [C2mim]+-based ionic liquids with the highest isolated yields found in [C2mim][NTf2]. The developed procedure allowed for a replacement of hazardous solvents such as benzene and acetonitrile which are commonly used for this transformation.
| ID Code: | 9904 |
|---|---|
| Item Type: | Article (Refereed Research - C1) |
| FoR Codes: | 03 CHEMICAL SCIENCES > 0305 Organic Chemistry > 030503 Organic Chemical Synthesis @ 100% |
| SEO Codes: | 97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100% |
| Deposited On: | 08 Apr 2010 15:54 |
| Last Modified: | 16 May 2013 01:07 |
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| Citation Counts with External Providers: | Web of Science: 4 |
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