Stereochemical influences on intervalence charge transfer in homodinuclear complexes of ruthenium
D`Alessandro, Deanna M., Kelso, Laurence, and Keene, F Richard (2001) Stereochemical influences on intervalence charge transfer in homodinuclear complexes of ruthenium. Inorganic Chemistry, 40 (26). pp. 6841-6844.
|PDF (Published version) - Repository staff only - Requires a PDF viewer such as GSview, Xpdf or Adobe Acrobat Reader|
View at Publisher Website: http://dx.doi.org/10.1021/ic010857c
The synthesis of polynuclear transition metal assemblies and their electrochemical, photochemical, and photophysical properties have attracted significant recent interest; this has been motivated largely by the potential of multicomponent systems as a basis of novel applicable materials.1 However, the existence of the stereochemical complexities inherent in such systems, and their influence on intramolecular energy- and electrontransfer processes, has not always been acknowledged^2.
Work in our laboratory has established synthetic methodologies for the isolation of the stereoisomers of a variety of mono-, di-, and trinuclear complexes^2,3. Significantly, this work has given rise to the first three examples of differences in the spectral, electrochemical, and photophysical properties of stereoisomers in such assemblies^2,4.
|Item Type:||Article (Refereed Research - C1)|
This publication does not have an abstract. The first two parapgraphs are displayed as the abstract.
|Keywords:||ruthenium; dinuclear; intervalence charge-transfer; IVCT; mixed-valence; stereochemistry|
|FoR Codes:||03 CHEMICAL SCIENCES > 0302 Inorganic Chemistry > 030207 Transition Metal Chemistry @ 100%|
|SEO Codes:||97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100%|
|Deposited On:||22 Feb 2010 14:52|
|Last Modified:||05 Oct 2012 13:20|
Last 12 Months: 0
Repository Staff Only: item control page