A new rearranged dolabellane diterpene from the soft coral Clavularia inflata
Alea, Glenn V., Bowden, Bruce F., and Ragasa, Consolacion Y. (2008) A new rearranged dolabellane diterpene from the soft coral Clavularia inflata. Natural Product Research, 22 (9). pp. 814-819.
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A new dolabellane type diterpene 1 has been isolated through its acetate 1a. The structure of 1a was elucidated by extensive 1D and 2D NMR spectroscopy and confirmed by mass spectrometry. The structure of 1 was deduced by comparison of its NMR spectral data with those of 1a, while its relative stereochemistry was deduced by NOESY. The absolute stereochemistry of C-7 was determined by analyses of 1 separately esterified with R and S O-mandelic acids.
|Keywords:||diterpenes; corals; natural products; NMR spectroscopy; stereochemistry; Clavularia inflata, (3Z,5E,1S*,7S,12aS*)-1-isopropyl1-6,12a-dimethyl-10-methylene-1,2,4,7,8,9,11,12,12a-nonahydrocyclopentacycloun decen-7-ol|
|FoR Codes:||03 CHEMICAL SCIENCES > 0305 Organic Chemistry > 030502 Natural Products Chemistry @ 100%|
|SEO Codes:||97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100%|
|Deposited On:||29 Mar 2010 12:09|
|Last Modified:||18 Oct 2013 00:52|
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