Ruthenium(II) complexes of chelating ligands containing benzoxazole and benzothiazole subunits: synthesis, X-ray crystallography, spectroscopy and electrochemistry

Richardson, Chris, Keene, F. Richard, and Steel, Peter J. (2008) Ruthenium(II) complexes of chelating ligands containing benzoxazole and benzothiazole subunits: synthesis, X-ray crystallography, spectroscopy and electrochemistry. Australian Journal of Chemistry, 61 (3). pp. 183-188.

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DOI: 10.1071/CH08021

View at Publisher Website: http://dx.doi.org/10.1071/CH08021

Abstract

Bis(2,2'-bipyridyl)ruthenium(ii) complexes of four chelating ligands that contain benzoxazole or benzothiazole rings have been prepared and characterized by NMR spectroscopy, visible absorption spectroscopy, electrochemical measurements and, in two cases, by X-ray crystallography. The incorporation of these ring systems has a marked effect on the electronic properties of the resulting complexes.

ID Code:5904
Item Type:Article (Refereed Research - C1)
Keywords:ruthenium; X-ray crystallography; benzoxazole; benzothiazole; electrochemistry; spectroscopy
FoR Codes:03 CHEMICAL SCIENCES > 0302 Inorganic Chemistry > 030207 Transition Metal Chemistry @ 100%
SEO Codes:97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100%
Deposited On:11 Feb 2010 14:40
Last Modified:14 May 2013 00:49
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