Rational ligand design for metal ion recognition. Synthesis of a N-benzylated N2S3-donor macrocycle for enhanced silver(I) discrimination

Vasilescu, Ioana M., Bray, David J., Clegg, Jack K., Lindoy, Leonard F., Meehan, George V., and Wei, Gang (2006) Rational ligand design for metal ion recognition. Synthesis of a N-benzylated N2S3-donor macrocycle for enhanced silver(I) discrimination. Dalton Transactions , 2006 (43). pp. 5115-5117.

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DOI: 10.1039/b613636m

View at Publisher Website: http://dx.doi.org/10.1039/b613636m

Abstract

Four previously documented ligand design strategies for achieving Ag(I) discrimination have been applied to the design of a new N-benzylated N2S3-donor macrocycle; the latter shows high selectivity for Ag(I) over Co(II), Ni(II), Cu(II), Zn(II), Cd(II) and Pb(II) in log K and bulk membrane transport studies.

ID Code:4596
Item Type:Article (Refereed Research - C1)
Keywords:metal ion recognition; silver; macrocycle; synthesis
FoR Codes:UNSPECIFIED
SEO Codes:97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100%
Deposited On:16 Jun 2009 08:24
Last Modified:18 Jun 2013 00:41
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