New heterotopic, linked macrocyclic systems derived from selectively protected macrocycles
Chartres, Jy D., Lindoy, Leonard F., and Meehan, George V. (2006) New heterotopic, linked macrocyclic systems derived from selectively protected macrocycles. Tetrahedron, 62 (17). pp. 4173-4187.
|PDF (Published Version) - Repository staff only - Requires a PDF viewer such as GSview, Xpdf or Adobe Acrobat Reader|
View at Publisher Website: http://dx.doi.org/10.1016/j.tet.2006.02....
The use of orthogonally protected cyclam and 1,9-dithia-5,13-diazacyclohexadecane macrocycles, in combination with aza-18-crown-6, has enabled the efficient synthesis of a new heterotritopic macrocyclic ligand incorporating N4-, N2S2- and NO5-donor sites. A similar strategy has allowed the incorporation of cyclam and 1,9-dithia-5,13-diazacyclohexadecane into a cofacial ligand. Further, the synthesis of novel tetramacrocyclic ligands has been achieved in which the macrocycles are linked in a cyclic arrangement. The availability of different binding sites in the respective products makes the latter suitable candidates for the synthesis of a range of mixed-metal multinuclear complexes.
|Item Type:||Article (Refereed Research - C1)|
|Keywords:||macrocycle; multi-nuclear; synthesis; linked macrocycle; cofacial; heterotopic; orthogonal protection; cyclam|
|SEO Codes:||97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100%|
|Deposited On:||15 Jun 2009 15:38|
|Last Modified:||21 May 2013 00:41|
Last 12 Months: 1
|Citation Counts with External Providers:||Web of Science: 11|
Repository Staff Only: item control page