Mobilisation of traffic-derived trace metals from road corridors into coastal stream and estuarine sediments, Cairns, northern Australia
Pratt, C., and Lottermoser, B.G. (2007) Mobilisation of traffic-derived trace metals from road corridors into coastal stream and estuarine sediments, Cairns, northern Australia. Environmental Geology, 52 (3). pp. 437-448.
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This investigation revealed the presence of traffic-derived metals within road, stream and estuarine sediments collected from a coastal catchment, northern Australia. Studied road sediments displayed variable total metal concentrations (median Cd, Cu, Pb, Pd, Pt, Ni and Zn values: 0.19, 42.6, 67.5, 0.064, 0.104, 36.7 and 698 mg/kg, respectively). The distinctly elevated Zn values are due to abundant tyre rubber shreds (as verified by SEM-EDS and correlation analysis). By comparison to the road sediments, background stream sediments taken upstream from roads have relatively low median Pb, Pd, Pt and Zn concentrations (7.3 mg/kg Pb, 0.01 mg/kg Pd, 0.012 mg/kg Pt, 62 mg/kg Zn). Stream and estuarine sediment samples collected below roads have median values of 21.8 mg/kg Pb, 0.014 mg/kg Pd, 0.021 mg/kg Pt and 71 mg/kg Zn, and exhibit 207Pb/206Pb and 208Pb/206Pb ratios that appear on a mixing line between the isotopically distinct background stream sediments and the road sediments. Thus, mobilisation of dusts and sediments from road surfaces has resulted in relatively elevated Pb, Pd, Pt and Zn concentrations and non-radiogenic Pb isotope ratios in local coastal stream and estuarine sediments. The investigation demonstrates that traffic-derived metals enter coastal stream and estuary sediments at the fringe of the Great Barrier Reef lagoon.
|Item Type:||Article (Refereed Research - C1)|
|Keywords:||traffic pollution; road sediments; stream sediments; metals; Pb isotopes; Australia|
|FoR Codes:||04 EARTH SCIENCES > 0403 Geology > 040306 Mineralogy and Crystallography @ 50%|
04 EARTH SCIENCES > 0402 Geochemistry > 040299 Geochemistry not elsewhere classified @ 50%
|SEO Codes:||96 ENVIRONMENT > 9609 Land and Water Management > 960999 Land and Water Management of Environments not elsewhere classified @ 100%|
|Deposited On:||08 May 2009 13:12|
|Last Modified:||18 Oct 2013 00:30|
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