Linked macrocylic systems. Interaction of copper(I) with tris-ring N2S2-donor macrocycles and their single-ring analogues
Groth, Andrew M., Lindoy, Leonard F., Meehan, George V., Skelton, Brian W., and White, Allan H. (2007) Linked macrocylic systems. Interaction of copper(I) with tris-ring N2S2-donor macrocycles and their single-ring analogues. Inorganic Chemistry Communications, 10 (9). pp. 1070-1073.
|PDF - Repository staff only - Requires a PDF viewer such as GSview, Xpdf or Adobe Acrobat Reader|
View at Publisher Website: http://dx.doi.org/10.1016/j.inoche.2007....
The interaction of two tri-linked N2S2-donor macrocyclic ligands, 1 (R = H) and 2 (R = H), and their related single ring derivatives, 3 (R = H) and 4 (R = CH2C6H5), with copper(I) is reported. Solid 3:1 (metal:ligand) complexes of type [Cu3L](PF6)3 (L = 1 and 2, R = H) and single ring derivatives of type [CuL]PF6 (L = 3, R = H; L = 4, R = CH2C6H5) were isolated; the X-ray structure of [CuL]PF6 (L = 3, R = H) showed that the four macrocyclic donor atoms coordinate to the copper(I) in a quasi-tetrahedral manner (Cu–N 2.089, 2.096(4); Cu–S 2.239, 2.264(2) Å, X–Cu–Y 104.5(1)–115.4(1))°.
|Item Type:||Article (Refereed Research - C1)|
|Keywords:||macrocycle; X-ray crystallography; copper(I); trinuclear; S2N2-donor macrocycle; Trinucleating macrocycle; X-ray|
|FoR Codes:||03 CHEMICAL SCIENCES > 0302 Inorganic Chemistry > 030207 Transition Metal Chemistry @ 100%|
|SEO Codes:||97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100%|
|Deposited On:||07 May 2009 16:46|
|Last Modified:||18 Oct 2013 00:26|
Last 12 Months: 0
|Citation Counts with External Providers:|
Repository Staff Only: item control page