Preparation of 7,8-diazaphencyclone and its use in the construction of rigid, space-separated 1,10-phenanthroline donor-acceptor systems: New ligands for metal complexation
Warrener, Ronald N., Houghton, Mark A., Schultz, Austin C., Keene, F. Richard, Kelso, Laurence S., Dash, Robert, and Butler, Douglas N. (1996) Preparation of 7,8-diazaphencyclone and its use in the construction of rigid, space-separated 1,10-phenanthroline donor-acceptor systems: New ligands for metal complexation. Chemical Communications, 1996 . pp. 1151-1152.
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DOI: 10.1039/CC9960001151
View at Publisher Website: http://dx.doi.org/10.1039/CC9960001151
Abstract
7,8-Diazaphencyclone 7 is used as a delivery reagent to fuse 1,10-phenanthroline groups onto alkenic centres of rigid spacer molecular racks (molracs); molrac alkenes containing redox-active donor-acceptor chromophores yield molrac diads whose metal complexes, e.g. 26, are suitable for mechanistic studies involving intramolecular electron transfer.
| ID Code: | 22835 |
|---|---|
| Item Type: | Article (Refereed Research - C1) |
| Keywords: | ruthenium |
| FoR Codes: | 03 CHEMICAL SCIENCES > 0302 Inorganic Chemistry > 030207 Transition Metal Chemistry @ 30% 03 CHEMICAL SCIENCES > 0303 Macromolecular and Materials Chemistry > 030306 Synthesis of Materials @ 70% |
| SEO Codes: | 97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100% |
| Deposited On: | 08 Aug 2012 14:04 |
| Last Modified: | 02 Jan 2013 12:32 |
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