Chiral [Ru(pp)₂(CO)₂]²⁺ species (pp = bidentate polypyridyl ligand) and their use in the stereoselective synthesis of ligand-bridge dinuclear complexes
Rutherford, Todd J., Quagliotto, Michael G., and Keene, F. Richard (1995) Chiral [Ru(pp)₂(CO)₂]²⁺ species (pp = bidentate polypyridyl ligand) and their use in the stereoselective synthesis of ligand-bridge dinuclear complexes. Inorganic Chemistry, 34 (15). pp. 3857-3858.
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View at Publisher Website: http://dx.doi.org/10.1021/ic00119a004
[Extract]The decarbonylation of chiral [Ru(pp)₂(CO)₂]²⁺ (pp = bidentate polypyridyl ligands) in the presence of excess pp shows stereoretention in the [Ru(pp)₃]²⁺ product, and under the same conditions, its reaction with chiral [Ru(pp')₂(BL)]²⁺ centers (pp and pp' may or may not be identical; BL = bridging ligand) allows synthesis of specific diastereoisomeric forms of the dinuclear species [(pp)₂Ru(BL)Ru(pp')₂]⁴⁺.
|Item Type:||Article (Refereed Research - C1)|
|FoR Codes:||03 CHEMICAL SCIENCES > 0302 Inorganic Chemistry > 030207 Transition Metal Chemistry @ 100%|
|SEO Codes:||97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100%|
|Deposited On:||16 Aug 2012 15:25|
|Last Modified:||02 Jan 2013 12:44|
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