Reduction of terminal alkynes mediated by tris(2,2'-bipyridine)cobalt(I)
Reitsma, David A., and Keene, F. Richard (1994) Reduction of terminal alkynes mediated by tris(2,2'-bipyridine)cobalt(I). Organometallics, 13 (4). pp. 1351-1354.
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In buffered aqueous ethanolic solution, phenylacetylene is reduced to styrene by [Co(bpy)₃]⁺ (bpy = 2,2'-bipyridine). In solutions of lower proton availability the predominant products were oligomeric, including coupled species such as 1,4-diphenylbutenyne.
|Item Type:||Article (Refereed Research - C1)|
|Keywords:||crystal-structure; complexes; hydrogenation; 1-alkynes; water; trans|
|FoR Codes:||03 CHEMICAL SCIENCES > 0302 Inorganic Chemistry > 030207 Transition Metal Chemistry @ 100%|
|SEO Codes:||97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100%|
|Deposited On:||16 Aug 2012 14:24|
|Last Modified:||02 Jan 2013 12:45|
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