Reduction of terminal alkynes mediated by tris(2,2'-bipyridine)cobalt(I)
Reitsma, David A., and Keene, F. Richard (1994) Reduction of terminal alkynes mediated by tris(2,2'-bipyridine)cobalt(I). Organometallics, 13 (4). pp. 1351-1354.
![[img]](http://eprints.jcu.edu.au/style/images/fileicons/application_pdf.png) | PDF (Published Version) - Repository staff only - Requires a PDF viewer such as GSview, Xpdf or Adobe Acrobat Reader 484Kb |
DOI: 10.1021/om00016a043
View at Publisher Website: http://dx.doi.org/10.1021/om00016a043
Abstract
In buffered aqueous ethanolic solution, phenylacetylene is reduced to styrene by [Co(bpy)₃]⁺ (bpy = 2,2'-bipyridine). In solutions of lower proton availability the predominant products were oligomeric, including coupled species such as 1,4-diphenylbutenyne.
| ID Code: | 22806 |
|---|---|
| Item Type: | Article (Refereed Research - C1) |
| Keywords: | crystal-structure; complexes; hydrogenation; 1-alkynes; water; trans |
| FoR Codes: | 03 CHEMICAL SCIENCES > 0302 Inorganic Chemistry > 030207 Transition Metal Chemistry @ 100% |
| SEO Codes: | 97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100% |
| Deposited On: | 16 Aug 2012 14:24 |
| Last Modified: | 02 Jan 2013 12:45 |
| Downloads: | Total: 0 Last 12 Months: 0 |
| Statistics: | More Statistics |
Repository Staff Only: item control page