Diastereoisomeric forms of ligand-bridged dimetallic diruthenium(II) and ruthenium(II)–osmium(II) species containing bidentate polypyridyl ligands
Reitsma, David R., and Keene, F. Richard (1993) Diastereoisomeric forms of ligand-bridged dimetallic diruthenium(II) and ruthenium(II)–osmium(II) species containing bidentate polypyridyl ligands. Dalton Transactions (18). pp. 2859-2860.
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DOI: 10.1039/dt9930002859
View at Publisher Website: http://dx.doi.org/10.1039/dt9930002859
Abstract
A new general synthetic route is reported for dinuclear species of the type [((L(subscript t)₂)RuL(subscript b)Ru(L(subscript t)')₂]⁴⁺ or [(L(subscript t))₂RuL(subscript b)Os(L(subscript t)')₂]⁴⁺(L(subscript t)' L(subscript t)'= bidentate polypyridyl ligands, L(subscript t)≠ L(subscript t)'; L(subscript b)= bridging ligand), together with the chromatographic separation and characterization of the diastereoisomeric pairs of the dimers.
| ID Code: | 22805 |
|---|---|
| Item Type: | Article (Refereed Research - C1) |
| Keywords: | electrochemical oxidation; luminescence; absorption; complexes |
| FoR Codes: | 03 CHEMICAL SCIENCES > 0302 Inorganic Chemistry > 030207 Transition Metal Chemistry @ 100% |
| SEO Codes: | 97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100% |
| Deposited On: | 16 Aug 2012 10:39 |
| Last Modified: | 02 Jan 2013 12:46 |
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