Resolution, X-ray structure and absolute configuration of a double-stranded helical diiron(II) bis(terpyridine) complex
Rapenne, Gwénaël, Patterson, Bradley T., Sauvage, Jean-Pierre, and Keene, F. Richard (1999) Resolution, X-ray structure and absolute configuration of a double-stranded helical diiron(II) bis(terpyridine) complex. Chemical Communications (18). pp. 1853-1854.
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DOI: 10.1039/a905135j
View at Publisher Website: http://dx.doi.org/10.1039/a905135j
Abstract
A dinuclear double helix constructed around two iron(II) bis(terpyridine) centres has been resolved by preparative column chromatography, several tens of milligrams of each enantiomer were obtained, with an excellent enantiomeric excess.
| ID Code: | 22804 |
|---|---|
| Item Type: | Article (Refereed Research - C1) |
| Keywords: | trinuclear complexes; ligands; stereoisomers; dinuclear; 1,4,5,8,9,12-hexaazatriphenylene; stereochemistry; diruthenium(II) ruthenium(ii) |
| FoR Codes: | 03 CHEMICAL SCIENCES > 0302 Inorganic Chemistry > 030207 Transition Metal Chemistry @ 100% |
| SEO Codes: | 97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100% |
| Deposited On: | 10 Aug 2012 15:00 |
| Last Modified: | 02 Jan 2013 12:27 |
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