Synthesis and properties of mononuclear tris(heteroleptic) osmium(II) complexes containing bidentate polypyridyl ligands
Jandrasics, Erik Z., and Keene, F. Richard (1997) Synthesis and properties of mononuclear tris(heteroleptic) osmium(II) complexes containing bidentate polypyridyl ligands. Dalton Transactions (2). pp. 153-159.
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DOI: 10.1039/a605161h
View at Publisher Website: http://dx.doi.org/10.1039/a605161h
Abstract
A general synthetic methodology has been elaborated for tris(bidentate ligand)osmium(II) complexes containing three different polypyridyl ligands. The tris(heteroleptic) complexes were characterized by NMR techniques, and the ligand dependence of their electrochemistry and electronic spectroscopy examined.
| ID Code: | 22775 |
|---|---|
| Item Type: | Article (Refereed Research - C1) |
| Keywords: | transfer excited-states; electronic-spectrum; carbonyl-complexes; redox; potentials; energy-gap; ruthenium(II); factorization ;parameters |
| FoR Codes: | 03 CHEMICAL SCIENCES > 0302 Inorganic Chemistry > 030207 Transition Metal Chemistry @ 100% |
| SEO Codes: | 97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100% |
| Deposited On: | 10 Aug 2012 10:11 |
| Last Modified: | 02 Jan 2013 12:35 |
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