Photooxygenations in a bubble column reactor
Yavorskyy, Alexander, Shvydkiv, Oksana, Limburg, Carolin, Nolan, Kieran, Delauré, Yan M.C., and Oelgemöller, Michael (2012) Photooxygenations in a bubble column reactor. Green Chemistry, 14 . pp. 888-892.
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DOI: 10.1039/C2GC16439F
View at Publisher Website: http://dx.doi.org/10.1039/C2GC16439F
Abstract
A novel column reactor was constructed and successfully applied to dye-sensitized photooxygenation reactions in aqueous alcohol solutions. The air flow pattern within the narrow glass column could be controlled via the size of the air inlet capillary. Using a 500 μm capillary, a slug flow pattern was realized which allowed for superior mass transfer and light transparency within a thin solvent layer. These features subsequently gave higher conversion rates and isolated yields.
| ID Code: | 21345 |
|---|---|
| Item Type: | Article (Refereed Research - C1) |
| FoR Codes: | 03 CHEMICAL SCIENCES > 0305 Organic Chemistry > 030504 Organic Green Chemistry @ 50% 03 CHEMICAL SCIENCES > 0305 Organic Chemistry > 030505 Physical Organic Chemistry @ 50% |
| SEO Codes: | 97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100% |
| Deposited On: | 10 Apr 2012 14:44 |
| Last Modified: | 18 May 2013 01:45 |
| Downloads: | Total: 3 Last 12 Months: 0 |
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| Citation Counts with External Providers: | Web of Science: 3 |
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