Microphotochemistry: 4,4'-Dimethoxybenzophenone mediated photodecarboxylation reactions involving phthalimides
Shvydkiv, Oksana, Nolan, Kieran, and Oelgemöller, Michael (2011) Microphotochemistry: 4,4'-Dimethoxybenzophenone mediated photodecarboxylation reactions involving phthalimides. Beilstein Journal of Organic Chemistry, 7 . pp. 1055-1063.
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DOI: 10.3762/bjoc.7.121
View at Publisher Website: http://dx.doi.org/10.3762/bjoc.7.121
Abstract
A series of 4,4'-dimethoxybenzophenone mediated intra- and intermolecular photodecarboxylation reactions involving phthalimides have been examined under microflow conditions. Conversion rates, isolated yields and chemoselectivities were compared to analogous reactions in a batch photoreactor. In all cases investigated, the microreactions gave superior results thus proving the superiority of microphotochemistry over conventional technologies.
| ID Code: | 17760 |
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| Item Type: | Article (Refereed Research - C1) |
| Additional Information: | © 2011 Shvydkiv et al; licensee Beilstein-Institut. This is an Open Access article under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (http://www.beilstein-journals.org/bjoc) |
| Keywords: | microflow; microreactor; photochemistry; photodecarboxylation; phthalimide |
| FoR Codes: | 03 CHEMICAL SCIENCES > 0305 Organic Chemistry > 030503 Organic Chemical Synthesis @ 30% 03 CHEMICAL SCIENCES > 0305 Organic Chemistry > 030505 Physical Organic Chemistry @ 20% 03 CHEMICAL SCIENCES > 0305 Organic Chemistry > 030501 Free Radical Chemistry @ 50% |
| SEO Codes: | 97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100% |
| Deposited On: | 11 Aug 2011 14:26 |
| Last Modified: | 17 May 2013 01:34 |
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| Citation Counts with External Providers: | Web of Science: 9 |
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