Back to the roofs – the solarchemical production of fine chemicals with sunlight
Oelgemöller, Michael, Jung, Christian, Ortner, Jürgen, Mattay, Jochen, Schiel, Christian, and Zimmermann, Elmar (2004) Back to the roofs – the solarchemical production of fine chemicals with sunlight. Proceedings of 2004 International Solar Energy Conference. ISEC 2004 International Solar Energy Conference , 11-14 July 2004, Portland, OR, USA , pp. 523-531.
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View at Publisher Website: http://dx.doi.org/10.1115/ISEC2004-65021
Three photochemical reactions were performed successfully under solar irradiation conditions: the photoacylation of quinones with aldehydes and the rose bengal sensitized photooxygenations of citronellol or 1,5-dihydroxynaphthalene. All reactions were easily performed on multigram to kilogram scales using cheap and commercially available starting materials, and yielded important key-intermediates for industrial applications.
|Item Type:||Conference Item (Refereed Research Paper - E1)|
Proceedings of the 2004 International Solar Energy Conference, Portland, OR, USA, 11-14 July 2004. ISBN:
|Keywords:||solarchemistry, production of fine chemicals, solar reactors, "Photo-Friedel-Crafts acylation", quinones, photooxygenations, citronellol, juglone|
|FoR Codes:||03 CHEMICAL SCIENCES > 0305 Organic Chemistry > 030503 Organic Chemical Synthesis @ 40%|
03 CHEMICAL SCIENCES > 0305 Organic Chemistry > 030504 Organic Green Chemistry @ 40%
03 CHEMICAL SCIENCES > 0305 Organic Chemistry > 030505 Physical Organic Chemistry @ 20%
|SEO Codes:||97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100%|
|Deposited On:||25 Aug 2011 10:00|
|Last Modified:||25 Aug 2011 10:00|
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