Back to the roofs – the solarchemical production of fine chemicals with sunlight

Oelgemöller, Michael, Jung, Christian, Ortner, Jürgen, Mattay, Jochen, Schiel, Christian, and Zimmermann, Elmar (2004) Back to the roofs – the solarchemical production of fine chemicals with sunlight. Proceedings of 2004 International Solar Energy Conference. ISEC 2004 International Solar Energy Conference , 11-14 July 2004, Portland, OR, USA , pp. 523-531.

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DOI: 10.1115/ISEC2004-65021

View at Publisher Website: http://dx.doi.org/10.1115/ISEC2004-65021

Abstract

Three photochemical reactions were performed successfully under solar irradiation conditions: the photoacylation of quinones with aldehydes and the rose bengal sensitized photooxygenations of citronellol or 1,5-dihydroxynaphthalene. All reactions were easily performed on multigram to kilogram scales using cheap and commercially available starting materials, and yielded important key-intermediates for industrial applications.

ID Code:17067
Item Type:Conference Item (Refereed Research Paper - E1)
Additional Information:

Proceedings of the 2004 International Solar Energy Conference, Portland, OR, USA, 11-14 July 2004. ISBN:

Keywords:solarchemistry, production of fine chemicals, solar reactors, "Photo-Friedel-Crafts acylation", quinones, photooxygenations, citronellol, juglone
ISBN:978-0-89553-176-6
FoR Codes:03 CHEMICAL SCIENCES > 0305 Organic Chemistry > 030503 Organic Chemical Synthesis @ 40%
03 CHEMICAL SCIENCES > 0305 Organic Chemistry > 030504 Organic Green Chemistry @ 40%
03 CHEMICAL SCIENCES > 0305 Organic Chemistry > 030505 Physical Organic Chemistry @ 20%
SEO Codes:97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100%
Deposited On:25 Aug 2011 10:00
Last Modified:25 Aug 2011 10:00
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