From conventional to microphotochemistry: photodecarboxylation reactions involving phthalimides
Shvydkiv, Oksana, Gallagher, Sonia, Nolan, Kieran, and Oelgemöller, Michael (2010) From conventional to microphotochemistry: photodecarboxylation reactions involving phthalimides. Organic Letters, 12 (22). pp. 5170-5173.
|PDF (Published Version) - Repository staff only - Requires a PDF viewer such as GSview, Xpdf or Adobe Acrobat Reader|
View at Publisher Website: http://dx.doi.org/10.1021/ol102184u
A series of acetone-sensitized photodecarboxylation reactions involving phthalimides have been investigated using conventional and microphotochemistry. Both, intra- and intermolecular transformations were compared. In all cases examined, the reactions performed in microreactors were superior in terms of conversions or isolated yields. These findings unambiguously prove the advantage of microphotochemistry over conventional photochemical techniques.
|Item Type:||Article (Refereed Research - C1)|
|FoR Codes:||03 CHEMICAL SCIENCES > 0305 Organic Chemistry > 030503 Organic Chemical Synthesis @ 50%|
03 CHEMICAL SCIENCES > 0305 Organic Chemistry > 030504 Organic Green Chemistry @ 20%
03 CHEMICAL SCIENCES > 0305 Organic Chemistry > 030505 Physical Organic Chemistry @ 30%
|SEO Codes:||97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100%|
|Deposited On:||10 May 2011 21:43|
|Last Modified:||23 May 2013 01:35|
Last 12 Months: 0
|Citation Counts with External Providers:||Web of Science: 19|
Repository Staff Only: item control page