Photosensitized addition of isopropanol to furanones in a continuous-flow dual capillary microreactor
Yavorskyy, Alexander, Shvydkiv, Oksana, Nolan, Kieran, Hoffmann, Norbert, and Oelgemöller, Michael (2011) Photosensitized addition of isopropanol to furanones in a continuous-flow dual capillary microreactor. Tetrahedron Letters , 52 (2). pp. 278-280.
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DOI: 10.1016/j.tetlet.2010.11.018
View at Publisher Website: http://dx.doi.org/10.1016/j.tetlet.2010....
Abstract
A novel continuous-flow photoreactor with parallel capillaries was constructed and successfully tested for the DMBP-sensitized addition of isopropanol to furanones. Complete conversions were achieved after a maximum of 10 min of irradiation with a single 350 nm lamp. The results were compared to analogous batch experiments using a conventional Rayonet chamber reactor equipped with 16 UVA lamps. The capillary tower generally showed higher space-time yields.
| ID Code: | 16783 |
|---|---|
| Item Type: | Article (Refereed Research - C1) |
| Keywords: | photoaddition; furanones; photochemistry; microreactor; microcapillary; continuous-flow synthesis |
| FoR Codes: | 03 CHEMICAL SCIENCES > 0305 Organic Chemistry > 030505 Physical Organic Chemistry @ 40% 03 CHEMICAL SCIENCES > 0305 Organic Chemistry > 030503 Organic Chemical Synthesis @ 40% 03 CHEMICAL SCIENCES > 0305 Organic Chemistry > 030504 Organic Green Chemistry @ 20% |
| SEO Codes: | 97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100% |
| Deposited On: | 16 Jun 2011 10:46 |
| Last Modified: | 23 May 2013 01:35 |
| Downloads: | Total: 3 Last 12 Months: 0 |
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| Citation Counts with External Providers: | Web of Science: 11 |
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