The shape of metallosupramolecular assemblies
Keene, F. Richard (2011) The shape of metallosupramolecular assemblies. Dalton Transactions, 40 (11). pp. 2405-2418.
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Despite original doubts on its feasibility, the control of the stereochemistry in ligand-bridged oligonuclear assemblies based on tris(bidentate) components has seen considerable progress in the last two decades, and differences have been observed in the physical characteristics of stereoisomers of such species. This retrospective review examines the background to this "stereochemical problem" and shows how the control of the stereochemical integrity of dinuclear and trinuclear ligand-bridged complexes has been utilised in studies of intramolecular electron transfer within the oligonuclear assemblies, and in probing the sequence- and structure-selectivity of the interaction of these species with nucleic acids.
|Item Type:||Article (Refereed Research - C1)|
|Keywords:||stereochemistry; chirality; oligonuclear; ruthenium|
|FoR Codes:||03 CHEMICAL SCIENCES > 0302 Inorganic Chemistry > 030207 Transition Metal Chemistry @ 90%|
03 CHEMICAL SCIENCES > 0302 Inorganic Chemistry > 030201 Bioinorganic Chemistry @ 10%
|SEO Codes:||97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100%|
|Funders:||Australian Research Council|
|Deposited On:||07 Jun 2011 16:01|
|Last Modified:||18 Oct 2013 01:12|
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