Synthesis, structure and optical characteristics of pyridyl substituted diketonates of lanthanoids
Brück, Stefan, Hilder, Matthias, Junk, Peter C., and Kynast, Ulrich H. (2000) Synthesis, structure and optical characteristics of pyridyl substituted diketonates of lanthanoids. Inorganic Chemistry Communications, 3 (11). pp. 666-670.
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Lanthanoid complexes of a dipyridylsubstituted β-diketonate ligand have been prepared and their structure and optical characteristics have been explored. The structure of these complexes are ten-coordinate centrosymmetric dimers with quadruply bridging diketonate ligands, terminal diketonate ligands and ‘dangling' and bound pyridyl nitrogen atoms. The europium complex diplays strongly luminescent properties while the terbium analogue is completely quenched.
|Item Type:||Article (Refereed Research - C1)|
|FoR Codes:||03 CHEMICAL SCIENCES > 0302 Inorganic Chemistry > 030202 f-Block Chemistry @ 100%|
|SEO Codes:||97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100%|
|Deposited On:||17 Jul 2012 11:42|
|Last Modified:||17 Jul 2012 11:42|
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