Photoacylations of 2-substituted 1,4-naphthoquinones: a concise access to biologically active quinonoid compounds
Waske, Prashant A., Mattay, Jochen, and Oelgemöller, Michael (2006) Photoacylations of 2-substituted 1,4-naphthoquinones: a concise access to biologically active quinonoid compounds. Tetrahedron Letters, 47 (8). pp. 1329-1332.
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DOI: 10.1016/j.tetlet.2005.12.060
View at Publisher Website: http://dx.doi.org/10.1016/j.tetlet.2005....
Abstract
Photochemical acylations of 2-substituted-1,4-naphthoquinones with various aldehydes furnished acylated hydroquinones and acylated quinones in moderate to good combined yields. All reactions are easily performed and open a rapid access to biologically active compounds. For the 2-methyl-1,4-naphthoquinone/butyraldehyde pair, a novel tri-keto compound has been additionally isolated.
| ID Code: | 10220 |
|---|---|
| Item Type: | Article (Refereed Research - C1) |
| Keywords: | Photoacylation; Quinones; Aldehydes; Addition reactions; Photochemistry. |
| FoR Codes: | 03 CHEMICAL SCIENCES > 0305 Organic Chemistry > 030503 Organic Chemical Synthesis @ 100% |
| SEO Codes: | 97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100% |
| Deposited On: | 16 Apr 2010 11:47 |
| Last Modified: | 09 Jun 2013 01:09 |
| Downloads: | Total: 1 Last 12 Months: 0 |
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| Citation Counts with External Providers: | Web of Science: 11 |
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