Photoacylations of 2-substituted 1,4-naphthoquinones: a concise access to biologically active quinonoid compounds
Waske, Prashant A., Mattay, Jochen, and Oelgemöller, Michael (2006) Photoacylations of 2-substituted 1,4-naphthoquinones: a concise access to biologically active quinonoid compounds. Tetrahedron Letters, 47 (8). pp. 1329-1332.
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Photochemical acylations of 2-substituted-1,4-naphthoquinones with various aldehydes furnished acylated hydroquinones and acylated quinones in moderate to good combined yields. All reactions are easily performed and open a rapid access to biologically active compounds. For the 2-methyl-1,4-naphthoquinone/butyraldehyde pair, a novel tri-keto compound has been additionally isolated.
|Item Type:||Article (Refereed Research - C1)|
|Keywords:||Photoacylation; Quinones; Aldehydes; Addition reactions; Photochemistry.|
|FoR Codes:||03 CHEMICAL SCIENCES > 0305 Organic Chemistry > 030503 Organic Chemical Synthesis @ 100%|
|SEO Codes:||97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100%|
|Deposited On:||16 Apr 2010 11:47|
|Last Modified:||29 Jul 2013 00:56|
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